Beilstein J. Org. Chem.2014,10, 921–928, doi:10.3762/bjoc.10.90
-9,10-dione, which is highly deactivated towards the electrophilic substitution is investigated. The peracid, nonanebis(peroxoicacid), possesses advantages such as better stability at room temperature, it is easy to prepare and non-shock sensitiv as compared to the conventional peracids. The present
protocol has a broad scope for the bromination of various substituted and unsubstituted aminoanthracene-9,10-diones.
Keywords: aminoanthracene-9,10-dione; benzanthrone; KBr; nonanebis(peroxoicacid); oxidative bromination; Introduction
The brominated aminoanthracene-9,10-dione derivatives and
issues. These peracids are either have to be prepared in situ or they require cold storage conditions [31]. Finding that there is a need to develop a stable peracid, we synthesized a stable, solid, aliphatic long chain peracid, nonanebis(peroxoicacid). This peracid is easy to synthesize and possesses
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Graphical Abstract
Scheme 1:
Aliphatic peracid mediated bromination of aminoanthracene-9,10-dinone.